Journal
DALTON TRANSACTIONS
Volume -, Issue 35, Pages 6960-6966Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b901195a
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Funding
- FCT of Portugal [REDE/1517/RMN/2005, REDE/1504/REM/2005, SFRH/BD/28490/2006]
- POCI 2010
- FEDER [PTDC/QUI/64458/2006]
- MEC of Spain [CTQ2008-04460]
- Bancaixa [P1.1B2007-04]
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A simple high-yielding method for the preparation of a tetramethylcyclopentadienyl-NHC ligand is described. This ligand has been successfully coordinated to Rh and Ir. A related Cp*-NHC ligand with a -CH2CMePh-linker between the Cp* and the NHC is also described, together with its coordination to Rh and Ir. This latter ligand, affords the orthocyclometallation of the phenyl ring yielding a constrained structure in which the ligand is tridentate. All the complexes have been fully characterized and their crystal structures are described. Preliminary catalytic results on the beta-alkylation of secondary alcohols and N-alkylation of aniline with primary alcohols are also reported.
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