4.7 Article

A monometallic tri-spin single-molecule magnet based on rare earth radicals

Journal

DALTON TRANSACTIONS
Volume -, Issue 40, Pages 8489-8492

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b908639k

Keywords

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Funding

  1. National Natural Science Foundation of China [20631030, 20871113, 50672037]
  2. National Basic Research Program of China (973 Program) [2007CB815305]
  3. Tianjin National Natural Science Foundation [09JCYBJC05500]

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A mononuclear tri-spin single-molecule magnet based on the rare earth radical [Tb(hfac)(3)(NITPhOEt)(2)] (NITPhOEt = 4'-ethoxy-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been synthesized, structurally characterized and the alternating current signals show a slow relaxation of magnetization and frequency-dependent signals.

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