Journal
DALTON TRANSACTIONS
Volume -, Issue 23, Pages 4432-4434Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b906393p
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Funding
- European Community [MRTN-CT-2003-503864]
- CNRS
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Generations 1 to 3 of dendrimers ended by water-soluble phosphines are synthesized and their ruthenium complexes are used as catalysts in aqueous media; a slightly positive dendritic effect on the regioselectivity is observed for hydration of alkynes and a large positive dendritic effect is observed in the biphasic (water/heptane) catalysed isomerisation of allylic alcohols to ketones where the products are easily isolated and the catalyst can be reused several times, even the first generation.
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