4.7 Article

Caesium-templated lanthanoid-containing polyoxotungstates

Journal

DALTON TRANSACTIONS
Volume -, Issue 23, Pages 4423-4425

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b902077b

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Funding

  1. Swiss National Science Foundation [PP002-114711/1]
  2. University of Zurich
  3. Australian Research Council

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A family of novel lanthanoid-containing polytungstoarsenate(III) polyanions with interesting structural features has been isolated: six lacunary {alpha-AsW9O33} building blocks comprising unusual pyramidal WO5 units are templated by a caesium cation in a central cavity of the structure.

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