Journal
DALTON TRANSACTIONS
Volume -, Issue 37, Pages 7805-7810Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b905621a
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A pentanuclear complex, [Mo(CN)(8){CuL1}(2){CuL1(H2O)}(2)]center dot 6H(2)O 1, and a decanuclear one, [Mo(CN)(8){CuL2}(3){CuL2(H2O)}](2)center dot 10H(2)O 2, have been obtained following the building- block approach (HL1 and HL2 are tridentate Schiff bases obtained by reacting salicylaldehyde with 2-aminomethylpyridine and 2-aminoethyl-pyridine, respectively). Both compounds present reversible photo-induced magnetic properties interpreted as a Mo-IV-Cu-II charge transfer. Compound 2 exhibits a lower efficiency of this metal-metal charge transfer than compound 1 attributed to a less flexible structure of 2 compared to 1.
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