Journal
DALTON TRANSACTIONS
Volume -, Issue 5, Pages 753-762Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b813383b
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Funding
- EPSRC [EP/E065392/1]
- Engineering and Physical Sciences Research Council [EP/E065392/1] Funding Source: researchfish
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The reactivity of alcohols can be enhanced by the temporary removal of hydrogen using a transition metal catalyst to generate an intermediate aldehyde or ketone. The so-formed carbonyl compound has a greater reactivity towards nucleophilic addition accommodating the in situ formation of imines or alkenes. The return of hydrogen from the catalyst leads to the formation of new C-N and C-C bonds, often with water as the only reaction by-product.
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