Journal
DALTON TRANSACTIONS
Volume -, Issue 16, Pages 2899-2908Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b819237e
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Transition metal complexes mediate beta-boration of alpha,beta-unsaturated carbonyl compounds highlighting the advantages of using inexpensive catalytic systems, (Cu, Ni), both in the catalytic activity and selectivity. The new C-beta-B bond can be accomplished in a stereoselective manner by modifying the metal complex with chiral ligands. Alternative mechanistic studies support the enantioselectivity observed, and large-scale applications of this reaction are currently being developed.
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