4.7 Article

First neodymium(III) alkyl-carbene complex based on bis(iminophosphoranyl) ligands

Journal

DALTON TRANSACTIONS
Volume -, Issue 46, Pages 10219-10222

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b918971h

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Funding

  1. CNRS
  2. Ecole Polytechnique

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Serendipitous deprotonation of bis(iminophosphoranyl) methanide Nd(III) complexes afforded the first alkyl-carbene neodymium complex. Due to the presence of structurally similar methanide and methandiide fragments, this complex features, as evidenced by X-ray crystallographic analysis, Nd-C single and multiple bonds.

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