4.7 Article

Sandwiched sodium and half-sandwiched copper carbonyl complexes featuring polyfluorinated tris(triazolyl)borate [HB(3,5-(CF3)(2)Tz)(3)](-)

Journal

DALTON TRANSACTIONS
Volume -, Issue 6, Pages 915-917

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b819463g

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Funding

  1. Welch Foundation [Y-1289]
  2. National Science Foundation [CHE-0701247]
  3. NSF-CRIF [CHE-0741936]

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Fluorinated tris(triazolyl) borate [HB(3,5-(CF3)(2)Tz)(3)](-) (Tz = triazolyl) affords the isolation of [ Na(THF)(6)]{[HB(3,5-(CF3) (2)Tz)(3)](2)Na} with a ligand sandwiched sodium ion and a copper carbonyl complex [HB(3,5-(CF3)(2)Tz)(3)]CuCO with a high C-O stretching frequency.

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