Journal
DALTON TRANSACTIONS
Volume -, Issue 44, Pages 9929-9934Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b914215k
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- Council of Scientific and Industrial Research, New Delhi, India [HRDG 01(2074)/EMR-II/2006]
- Spanish Government [CTQ 2006/03949]
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The first examples of homo- and heteroleptic complexes containing 5-ferrocenyldipyrromethene (fcdpm) [Cu(fcdpm)(2)] (1) [Cu(fcdpm)(acac)] (2), [Ni(fcdpm)(acac)] (3) and [Zn(fcdpm)(2)] (4) (acac = acetylacetonato) are described. Formation of the asymmetric metal complexes has been followed by electronic absorption and infrared spectroscopy. The complexes have been characterised by elemental analyses and spectral studies. Structures of [Cu(fcdpm)(2)] (1), [Cu(fcdpm)(acac)] (2) and [Ni(fcdpm)(acac)] (3) have been determined crystallographically. Structural data revealed that the metal centre in the copper complexes [Cu(fcdpm)(2)] (1), [Cu(fcdpm)(acac)] (2) and the nickel complex [Ni(fcdpm)(acac)] (3) adopts a distorted square planar geometry.
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