Journal
DALTON TRANSACTIONS
Volume -, Issue 41, Pages 5567-5569Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b812605b
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Funding
- French National Research Agency
- ANR [07-BLAN-0298-01]
- Life Science Division of the CEA (BioHydrogen Program)
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Quantum yield values up to 16% under visible irradiation associated with high turnover frequencies (similar to 50 h(-1)) and stability (up to 273 turnovers), characterize the new photocatalytic systems for hydrogen production, based on diimine derivatives of ruthenium, cyclometallated iridium or tricarbonylrhenium as photosensitizers and cobaloxime H-2-evolving catalytic centers, which are among the most efficient molecular systems reported so far and compete with some platinum-based systems.
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