Journal
DALTON TRANSACTIONS
Volume -, Issue 44, Pages 6113-6116Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b812113c
Keywords
-
Categories
Funding
- NNSF of China [20671079, 20721001]
- Chinese Ministry of Education [107068]
- NECTFJ
- MSTC [2007CB815301]
Ask authors/readers for more resources
Solvothermal reaction of Co(OAc)(2)center dot 4H(2)O with H(4)L (H = 2-((2-hydroxybenzylidene)amino)-2-hydroxymethylpropane-1,3-diol) in MeCN gave a mixed-valence pentanuclear cobalt complex [Co(5)(HL)(2)(H(2)L)(2)(OAc)(2)]center dot 2.5H(2)O. Crystal structural analysis revealed that two Co(III) ions were linked to a central triangular Co(II) core through HL(3-) and H(2)L(2-) hydroxyl groups. Magnetic measurements showed interesting magnetic properties that were assigned to spin-orbital coupling and ferromagnetic exchange interactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available