Journal
DALTON TRANSACTIONS
Volume -, Issue 42, Pages 5698-5700Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b809545k
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Funding
- Natural Science Foundation of Shaanxi Province [2006B21]
- Education Commission of Shaanxi Province [07JK404]
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The polyanions [Cr-2(AsMo7O27)(2)](12-) (1a) or [Cu-2(AsMo7O27) (2)](14-) (2a) have sandwich-like structures wrapping two transition metals between two [As(III) Mo7O27](9-) fragments, and the fragment is unprecedented and can be viewed as a mono-capped hexavacant B-alpha-Keggin subunit with a central AsO3 group.
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