Journal
DALTON TRANSACTIONS
Volume -, Issue 20, Pages 2667-2669Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b801030g
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Rare-earth metal tris(borohydrides) [Ln(BH(4))(3)(thf)(3)] (Ln = Y, La, Nd, Sm) are converted with one equivalent of the Bronsted acid [NEt(3)H](+)[BPh(4)](-) in thf into the monocationic bis(borohydride) complexes [Ln(BH(4))(2)(thf)(5)](+)[BPh(4)](-). They efficiently initiate the ring-opening polymerisation of epsilon-caprolactone.
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