Journal
DALTON TRANSACTIONS
Volume -, Issue 34, Pages 4549-4551Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b809366k
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- National Science Foundation [CHE-0132680]
- Fannie and John Hertz Foundation
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The reaction of zirconium(IV) porphyrinogen with water yields a dinuclear complex in which one mu-oxo ligand bridges two Zr-IV centres, and two protons are bound to the alpha carbons of two porphyrinogen pyrroles. The reaction establishes the utility of the porphyrinogen macrocycle as a storage site for protons as well as electrons.
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