Journal
DALTON TRANSACTIONS
Volume -, Issue 34, Pages 4659-4663Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b807259k
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- Italian Ministry of University and Research [2005035123]
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Transfer hydrogenation from 2-propanol to CO/4-methylstyrene and CO/styrene polyketones was catalyzed by [Ir(diene)(N-N)X] (N-N = nitrogen chelating ligand; X = halogen) in the presence of a basic cocatalyst. The reactions were performed using dioxane as cosolvent, in order to overcome problems due to low polyketone solubility. The polyalcohols were obtained in yields up to 95%, the conversions being markedly dependent on the nature of the ligands coordinated to iridium as well as on the experimental conditions.
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