Journal
CURRENT ORGANIC CHEMISTRY
Volume 15, Issue 18, Pages 3263-3290Publisher
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/138527211797247996
Keywords
polythiophenes; C-C and C-X bond formation; palladium-catalyzed cross-coupling reactions; polymerization; Stille; Sonogashira
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Funding
- National Science Foundation [CHE-0924324]
- EPSRC [EP/H004408/1]
- American Chemical Society
- Engineering and Physical Sciences Research Council [EP/H004408/1] Funding Source: researchfish
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The synthesis of well-defined macromolecules using polymerization processes is a challenging and important task in organic chemistry. Palladium-catalyzed cross-coupling reactions represent an important tool in the chemist's armory, combining high efficiency, low catalyst loadings, high tolerance to a variety of functional groups and solvents and moderate reaction temperatures (25-100 degrees C). The present review is an account of the recent literature involving Pd-catalyzed, cross-coupling based polymerizations for the synthesis of polythiophenes, as well as the use of this and related compounds in polymer and material science.
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