Journal
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE
Volume 18, Issue 6, Pages 517-523Publisher
ELSEVIER SCIENCE LONDON
DOI: 10.1016/j.cocis.2013.10.001
Keywords
Polyelectrolytes; Adsorption; Charge reversal; Like-charge attraction; Molecular dynamics simulations; Monte Carlo simulations; Hydrogen bonding; Hydrophobic effect
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Funding
- Consejeria de Innovacion, Ciencia y Empresa de la Junta de Andalucia [P09-FQM-4698]
- Spanish Government [MAT2012-36270-004-02, MAT2012-36270-004-04, FIS2011-13051-E, CONSOLIDER-NANOSELECT-CSD2007-00041]
- Catalan Government [2009SGR164]
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In this review, we discuss the competition of non-DLVO forces in the adsorption of polyelectrolytes onto charged surfaces. We consider two particularly illustrative problems, namely the adsorption of polyelectrolytes onto similarly charged surfaces and the reversal of surface charge by adsorption of polyelectrolytes. Emphasis is made on how simulation results help to understand relevant experimental situations. (C) 2013 Elsevier Ltd. All rights reserved.
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