Structural and electrical studies of template synthesized copper nanowires

The template strategy combined with electrodeposition technique has been used to produce copper nanowires in the cylindrical pores of track-etched polycarbonate membranes. X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) and UV-visible spectroscopy have been used to characterize as-prepared copper nanowires. XRD study shows the face centered cubic crystal structure of copper nanowires. Williamson-Hall (WH) analysis has been used to determine the crystallite size and microstrain induced due to lattice deformation. FESEM results reveal that copper nanowires are continuous, well aligned with uniform diameter and having high aspect ratio. The optical absorption spectra exhibit a strong peak at 568 nm attributed to the surface plasmon resonance. The current-voltage (I-V) characteristics show an ohmic behavior of the fabricated copper nanowires. The increase in resistivity of nanowires than that of bulk counterpart has been attributed to the surface and size effects in nanowires and explained in the light of Fuchs-Sondeimer and Mayadas-Shatzkes models. (C) 2014 Elsevier B.V. All rights reserved.