4.4 Article

Determination of solid-liquid interfacial energy for a solid Sn in equilibrium with a Sn-Ag-Zn eutectic liquid

Journal

CURRENT APPLIED PHYSICS
Volume 11, Issue 4, Pages 1060-1066

Publisher

ELSEVIER
DOI: 10.1016/j.cap.2011.01.033

Keywords

Metals and alloys; Surfaces and interfaces; Crystal growth; Phase transitions

Funding

  1. Erciyes University Scientific Research Project Unit [FBA-10-2891]

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The equilibrated grain boundary groove shapes for a solid Sn in equilibrium with a Sn-Ag-Zn eutectic liquid were observed in a linear temperature gradient by using a Bridgman type directional solidification apparatus. The Gibbs-Thomson coefficient, solid-liquid interfacial energy and grain boundary energy for a solid Sn in equilibrium with a Sn-Ag-Zn eutectic liquid were determined to be (8.21 +/- 0.7) x 10(-8) Km, (116.2 +/- 15.1) x 10(-3) J m(-2) and (228.1 +/- 34.2) x 10(-3) J m(-2), respectively from observed grain boundary groove shapes. A comparison of present results with the previous experimental and theoretical results for similar solids in equilibrium with the different liquid was also made. (C) 2011 Elsevier B.V. All rights reserved.

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