Journal
CRYSTENGCOMM
Volume 16, Issue 27, Pages 5989-5992Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce00740a
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Funding
- MOE [RG 16/12, ARC 20/12, ARC 2/13]
- NRF, Singapore
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A new copper-silver-thiostannate, [enH][Cu2AgSnS4] (1), has been successfully synthesized under solvothermal conditions. Compound 1 features a quaternary two dimensional anionic [Cu2AgSnS4](-)layer, where Cu+ ions adopt a trigonal coordination mode and the Ag+ ion has a tetrahedral configuration. The photoelectrochemical studies indicate that 1 is photoactive and exhibits p-type semiconductor characteristics under visible light illumination.
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