Journal
CRYSTENGCOMM
Volume 16, Issue 34, Pages 7860-7864Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce00867g
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Funding
- NSFC of China [21001022, 21171033, 21131001, 21222105]
- PhD Station Foundation of Ministry of Education [20100043110003]
- Fundamental Research Funds for the Central Universities [12SSXT142]
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The first example of 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag20S10 nanoclusters, {[(CO32-) @Ag-20((SBu)-Bu-t)(10)(CH3COO)(8)(DMF)(2)]center dot 2H(2)O}(n) (1), is reported. Compound 1 is stable both in the solid state and in solution. It exhibits potential wide gap semiconductor properties, reversible thermochromic luminescence behaviour and excellent electrochemical properties.
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