Journal
CRYSTENGCOMM
Volume 16, Issue 29, Pages 6530-6533Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce01031k
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Funding
- Science and Industry Endowment Fund (SIEF)
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- International Synchrotron Access Program (ISAP)
- Australian Government
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The water-stable zirconium-tricarboxylate series of frameworks, [Zr6O4(OH)(4)(X)(6)(btc)(2)]center dot nH(2)O, where X = formate (F), acetate (A), or propionate (P), exhibit tunable porosity by virtue of systematic modulation of the chain length of the monocarboxylate ligand X. This modification not only impacts the pore size of the framework, but provides an important avenue for the construction of mixed-linker MOFs.
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