4.7 Article

Facile synthesis of porous MnCo2O4.5 hierarchical architectures for high- rate supercapacitors

Journal

CRYSTENGCOMM
Volume 16, Issue 12, Pages 2335-2339

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce42581a

Keywords

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Funding

  1. National Natural Science Foundation of China [21171035, 51302035]
  2. Key Grant Project of Chinese Ministry of Education [313015]
  3. PhD Programs Foundation of the Ministry of Education of China [20110075110008, 20130075120001]
  4. National 863 Program of China [2013AA031903]
  5. Science and Technology Commission of Shanghai Municipality [13ZR1451200]
  6. Program for Changjiang Scholars and Innovative Research Team in University [IRT1221]
  7. Hong Kong Scholars Program, the Fundamental Research Funds for the Central Universities
  8. Shanghai Leading Academic Discipline Project [B603]
  9. Program of Introducing Talents of Discipline to Universities [111-2-04]

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Porous urchin-like MnCo2O4.5 hierarchical architectures (similar to 4-6 mu m in diameter) synthesized by a facile hydrothermal route followed by a calcination process exhibited a specific capacitance of 151.2 F g(-1) at 5 mV s(-1), outstanding rate capability with 83.6% specific capacitance retention even when the current density is increased 50 times and excellent long-term cycle stability at progressively varied current densities and could be considered as a potential mixed transition metal oxide material for high-rate supercapacitors in some special applications that do not require a high capacitance.

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