4.7 Article

One-pot synthesis of Pd-Pt@Pd core-shell nanocrystals with enhanced electrocatalytic activity for formic acid oxidation

Journal

CRYSTENGCOMM
Volume 16, Issue 13, Pages 2560-2564

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce42536c

Keywords

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Funding

  1. NSFC [21361005, 21073152, 21373175]
  2. Fujian Provincial Department of Science and Technology [2008F3099]
  3. Foundation for the Talents by the Guizhou University [X060025]
  4. Natural Science Foundation of Guizhou Province [20072013]

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Well-defined Pd-Pt@Pd core-shell nanocrystals with a Pd-Pt alloy core and a conformal Pd shell of similar to 2-3 nm were directly synthesized through a one-pot, aqueous solution approach without any preformed Pd or Pt seeds. These Pd-Pt@Pd core-shell nanocrystals show an enhanced electrocatalytic activity for formic acid oxidation compared with commercial Pd black.

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