Journal
CRYSTENGCOMM
Volume 16, Issue 29, Pages 6523-6525Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce00504j
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Funding
- State Program of R. Moldova [14.518.02.04 A]
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The assembly of charge-neutral mixed-valent coordination clusters [(Mn2Mn4O2)-Mn-III-O-II(RCOO)(10)] (R = CHMe2, CMe3) and rigid isonicotinamide or semi-rigid aldrithiol-4 exo-bridging ligands results in (4,4) layers and a 2D bilayer containing an unprecedented type of cluster-based 'T-shaped' motif.
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