4.7 Article

Two porous metal-organic frameworks containing zinc-calcium clusters and calcium cluster chains

Journal

CRYSTENGCOMM
Volume 16, Issue 37, Pages 8664-8668

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce01237b

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Funding

  1. Korea CCS R&D Center (KCRC) grant - Korea government (Ministry of Science, ICT & Future Planning) [NRF-2012-0008900]

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A two-dimensional metal-organic framework (MOF) containing both Zn(II) and Ca(II) centres and a three-dimensional MOF containing only Ca(II) centres have the largest surface areas (BET 1560 and 914 m(2) g(-1), respectively) among the reported Ca-based MOFs and also exhibit high gas uptake up to 1 bar for H-2 at 77 K and CO2 at 298 K.

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