4.7 Article

A microporous metal-organic framework with Lewis basic pyridyl sites for selective gas separation of C2H2/CH4 and CO2/CH4 at room temperature

Journal

CRYSTENGCOMM
Volume 15, Issue 26, Pages 5232-5235

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce40452h

Keywords

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Funding

  1. Welch Foundation [AX-1730]
  2. NSFC [21273033, 21203024]
  3. Award 'MinJiang Scholar Program' in Fujian Province, China

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A microporous metal-organic framework [Eu(PDC)(1.5)(DMF)]center dot(DMF)(0.5)(H2O)(0.5) (UTSA-5, PDC = 3,5-pyridinedicarboxylate) with pyridyl sites on the pore surface has been realized to exhibit high C2H2/CH4 and CO2/CH4 separation at room temperature.

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