Journal
CRYSTENGCOMM
Volume 15, Issue 37, Pages 7589-7597Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce41256c
Keywords
-
Categories
Funding
- National Natural Science Funds for Distinguished Young Scholars [51025211]
- National Basic Research Program [2013CB934303]
- National Nature Science Foundation of China [51272137]
- Tai Shan Scholar Foundation of Shandong Province
Ask authors/readers for more resources
We developed a facile infiltration chemical route to fabricate nanocomposites with SnO2 nanoparticle embedded ordered mesoporous carbon (SnO2@OMC) as anode materials for lithium-ion batteries application. The content of SnO2 in the composites can be optimized by changing the mass ratio of SnCl2 center dot 2H(2)O to OMC. The as-prepared materials were characterized by X-ray diffraction, N-2 adsorption-desorption analysis techniques, field emission scanning electron microscopy, and high resolution transmission electron microscopy. Electrochemical performance results reveal that the SnO2@OMC composite containing 20 at% SnO2 displays an extraordinary reversible capacity up to 769 mA h g(-1) and a high coulombic efficiency up to nearly 98.7% even after 60 cycles at a high current density of 100 mA g(-1). Meanwhile, SnO2@OMC composite exhibits excellent rate capabilities. Even at a current rate as high as 1600 mA g(-1), it still maintains a stable charge-discharge capacity of 440 mA h g(-1) after 60 cycles. The outstanding electrochemical performance of the synthesized SnO2@OMC composites could be ascribed to its unique structural characteristics. The SnO2@OMC nanocomposites are promising candidates as anode materials for rechargeable lithium-ion batteries.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available