Journal
CRYSTENGCOMM
Volume 15, Issue 11, Pages 2067-2075Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce26494g
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Funding
- ANR, Aix-Marseille University [JCJC-2010-1001-1 Covanet]
- centre national de la recherche scientifique (CNRS)
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A series of substituted 1,4-benzenediboronic acids (BDBA) was synthesized and their thermal properties investigated. Two diboronic acids were studied as building-blocks for covalent organic framework (COF) formation, namely 2,5-dimethoxy-1,4-benzenediboronic acid and 2-nitro-1,4-benzeneboronic acid. Interestingly, substitution of the BDBA core caused a dramatic decrease of the polymerization temperature leading to the formation of a less organized structure.
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