Journal
CRYSTENGCOMM
Volume 15, Issue 27, Pages 5526-5531Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce40340h
Keywords
-
Categories
Funding
- National Basic Research Program of China [2011CB932303, 2011CB933101, 2012CB933001]
- National Natural Science Foundation of China [21073048, 51173031, 91127043, 51103094, 20933008]
- Natural Science Foundation of Tianjin and Youth Science Foundation [12JCQNJC01900]
- Doctor Project for Young Teachers of Ministry of Education [20110032120021]
- Key Laboratory of Optoelectronic Materials Chemistry and Physics, Chinese Academy of Sciences [2008DP173016, 2010KL0010]
- Research Start-up Funding for the Introduction of Talents, Institute of High Energy Physics, Chinese Academy of Sciences [2011IHEPYJRC504]
Ask authors/readers for more resources
5,10,15,20-Tetrakis(4-tetradecylphenyl)-porphyrin (P14) has been synthesized and its self-assembling behavior on highly oriented pyrolytic graphite (HOPG) surfaces when coadsorbing with tetradecane molecules have been investigated in this work. Scanning tunneling microscope (STM) studies show that the phthalocyanine (Pc) and copper(II) 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecafluoro-29H,31H-phthalocyanine (F16CuPc) can be immobilized by the network formed from P14 and consequently lead to two kinds of well-defined hybrid porphyrins and phthalocyanines hybrid nano-arrays. Interestingly, F16CuPc could form multilayer structure. The theoretical simulation results show that pi-pi stacking interactions and C-H center dot center dot center dot F-C hydrogen bonding between P14 and F16CuPc play a major role in stabilizing the P14/F16CuPc alternating single-/multi-layer architecture.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
