Journal
CRYSTENGCOMM
Volume 15, Issue 28, Pages 5598-5601Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce40519b
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Funding
- NSFC [21061009]
- Inner Mongolia Autonomous Region Funds for Grasslands Outstanding Talents Project
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Homochiral crystallizations of single-stranded helical coordination polymers were constructed using the V-shaped bridging ligand dicyanamide (mu(1,5)-dca(-)) and chelate auxiliary ligands. The enantiomeric nature of 1 and 2 is directly induced by the chirality of the auxiliary ligands. Whereas, the homochirality feature for 3 stems from the spontaneous symmetry breaking in crystallization.
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