4.7 Article

Practical microwave-induced hydrothermal synthesis of rectangular prism-like CaTiO3

Journal

CRYSTENGCOMM
Volume 15, Issue 13, Pages 2359-2362

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ce27040h

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Funding

  1. Global Research Laboratory program of the National Research Foundation of Korea
  2. CONACYT

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The crystalline phase transition from tetragonal TiO2 anatase and rutile structures to an orthorhombic unit cell of CaTiO3 was achieved using a microwave-assisted hydrothermal process. FESEM and HRTEM Images show a well faceted CaTiO3 rectangular-prism morphology. The use of a urea solution during the hydrothermal process allows the direct transformation of TiO2 to perovskite-like with exposed (111) and (202) facets.

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