4.7 Article

Accessing functionalized porous aromatic frameworks (PAFs) through a de novo approach

Journal

CRYSTENGCOMM
Volume 15, Issue 8, Pages 1515-1519

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce26595h

Keywords

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Funding

  1. Dow Chemical Company
  2. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) [DE-FG36-08GO18137/A001]
  3. DOE-EERE Postdoctoral Research Awards under the EERE Fuel Cell Technologies Program
  4. DTRA [HDTRA1-10-1-0023]
  5. NSF [DGE-0824162]
  6. NSF-NSEC
  7. NSF-MRSEC
  8. Keck Foundation
  9. state of Illinois
  10. Northwestern University

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Methyl-, hydroxymethyl-, and phthalimidomethyl-functionalized versions of the porous organic polymer PAF-1 have been obtained through de novo synthesis. The CO2 adsorption capacity of PAF-1-CH2NH2, obtained through the post-synthesis deprotection of PAF-1-CH2-phthalimide, has been shown to exceed that of PAF-1.

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