Journal
CRYSTENGCOMM
Volume 14, Issue 20, Pages 6957-6961Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce26046h
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Funding
- Korea Center for Artificial Photosynthesis (KCAP) located in Sogang University
- Ministry of Education, Science, and Technology (MEST) through the National Research Foundation of Korea [NRF-2009-C1AAA001-2009-0093879]
- Collaborative Research Project under the NRF-NSFC Cooperative Program from National Research Foundation
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In this paper, dendritic iron wire array films with different morphologies were prepared on Cu/ITO and slide ITO glass substrates by electrodeposition. The morphologies of Fe films obtained at different conditions were characterized by scanning electron microscopy. The growth mechanism of the dendritic Fe array is described by changing the ratio of deposition rate to mass transport rate (R) according to the experimental results. The variable R affects the final structure of the products. Especially, Fe dendrites can grow vertically layer by layer. The photoelectrochemical properties indicate that dendritic hematite (alpha-Fe2O3) arrays have a poor electron-hole (e-h) recombination effect.
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