Journal
CRYSTENGCOMM
Volume 14, Issue 6, Pages 2245-2250Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06423e
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Funding
- NSFC [20833010]
- National Basic Research Program of China [2011CB935900]
- NCET
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Hydro- and/or solvo-thermal nanocrystallization of lithium iron phosphate (LiFePO4) has been well recognized as an effective pathway to improve its electrochemical performances. Herein, it is reported that high-performance LiFePO4 single-crystalline nanoparticles have been successfully prepared by the additive-free solvothermal reaction and subsequent glucose-assisted calcination. In comparison with the similar hydrothermal reaction, the presence of ethylene glycol can unexpectedly induce the formation of gel-like intermediates at the time interval of 0.5 h, resulting in LiFePO4 nanoparticles with a three-dimensional (3D) lattice structure and an amorphous nanocoating for a reaction time of 2 h. Interestingly, the lattice structure of growing LiFePO4 crystals can be thoroughly damaged under the irradiation of an electron beam. Furthermore, after the continuous crystal growth and subsequent heat-treatment, nanocrystalline LiFePO4 can achieve a discharge capacity of similar to 165 mAh g(-1) at 0.1 C in assembled LiFePO4/Li half-cells, proving a successful nanocrystal-forming engineering of LiFePO4 for a lithium-ion battery cathode.
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