4.7 Article

Topotactic transformation of single-crystalline TiOF2 nanocubes to ordered arranged 3D hierarchical TiO2 nanoboxes

Journal

CRYSTENGCOMM
Volume 14, Issue 14, Pages 4578-4581

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25271f

Keywords

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Funding

  1. National Science Foundation of China [51002091, 20973102, 51021062]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20100131120028]
  3. National Basic Research Program of China [2007CB613302]

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3D hierarchical TiO2 nanoboxes, enclosed by six ordered arranged TiO2 nanorod arrays, were prepared via a template-engaged topotactic transformation process from TiOF2 nanocubes. The lattice matching between TiOF2 and anatase TiO2 was regarded as the key for the preferential growth and ordered arrangement of the TiO2 nanorods.

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