4.7 Article

Honeycomb frameworks with a very large mesh of 39 x 29 Å diameters stabilized by π-stacked coronene molecules

Journal

CRYSTENGCOMM
Volume 14, Issue 17, Pages 5398-5401

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce25806d

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology, Japan [21350032, 24245012, 24108714]
  2. Sumitomo Foundation
  3. Asahi Glass Foundation
  4. Grants-in-Aid for Scientific Research [24108714] Funding Source: KAKEN

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The assembly of linear edges and triangle nodes in a 3 : 2 molar ratio possibly forms a honeycomb topology: this was achieved by the use of paddlewheel-type dimetal complexes and 2,4,6-tris(4-pyridyl)-1,3,5-triazine, in which the framework with a very large mesh of 39 x 29 angstrom diameters was stabilized by pi-stacked coronene molecules.

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