Journal
CRYSTENGCOMM
Volume 14, Issue 12, Pages 4153-4156Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ce06701c
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Funding
- CSIR
- Government of India
- Grants-in-Aid for Scientific Research [23750157] Funding Source: KAKEN
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A simple room temperature reaction of Cu(NO3)(2), and 2,3-pyrazinedicarboxylic acid (H(2)pyzdc) in the presence of dihydroxyfumaric acid (DHFA) resulted in the formation of a highly stable 3D Cu(I) coordination polymer, {[Cu-2(pyzdc)]center dot 0.83H(2)O}(n) where DHFA acts as a reducing agent. It possesses a 1D water filled channel along the crystallographic c direction and the framework shows reversible single-crystal-to-single-crystal structural transformation upon dehydration and rehydration.
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