4.7 Article

Size-controlled synthesis of MIL-101(Cr) nanoparticles with enhanced selectivity for CO2 over N-2

Journal

CRYSTENGCOMM
Volume 13, Issue 23, Pages 6916-6919

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce06274c

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Funding

  1. EPSRC
  2. Engineering and Physical Sciences Research Council [EP/H046305/1] Funding Source: researchfish
  3. EPSRC [EP/H046305/1] Funding Source: UKRI

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Nanoparticles of MIL-101(Cr) have been fabricated using a hydrothermal method for the first time. The particle size can be controlled from 19 (4) nm to 84 (12) nm, by using a monocarboxylic acid as a mediator. These nano MIL-101(Cr) materials exhibit higher selectivities for CO2 over N-2 than bulk MIL-101(Cr).

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