Journal
CRYSTENGCOMM
Volume 13, Issue 17, Pages 5423-5427Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05388d
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Funding
- AFOSR [FA9550-05-1-0276]
- State of Ohio (WCI-PVIC), NSF [DMR-1006761, EXP-LA 0731153, CHE 0750303]
- BGSU
- NSF CRIF [0741973]
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The single crystals of 9-phenyl-9-dibenzophosphole chalcogenides {oxide (1), sulfide (2) and selenide (3)} and a mixed crystal of 2 and 3 have been prepared and characterized by X-ray diffraction analysis. Several intermolecular interactions such as pi-pi and Se-H were observed in the mixed crystal of 2 and 3. The mixed crystal of 2 and 3 exhibited enhanced phosphorescence compared to the pure constituent crystal (2 or 3) at low temperature.
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