4.7 Article

Synthesis of highly b-oriented zeolite MFI films by suppressing twin crystal growth during the secondary growth

Journal

CRYSTENGCOMM
Volume 13, Issue 11, Pages 3657-3660

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05094j

Keywords

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Funding

  1. Zhejiang Nature Science Foundation (ZJNSF) [R4090099]
  2. Science and Technology Department of Zhejiang Province [2009R50020]
  3. China Postdoctoral Science Foundation [20090461362, 201003718]
  4. Open Fund of the State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology

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Highly b-oriented MFI films are synthesized by simply controlling TPA(+) concentration of the secondary synthesis solution to suppress the formation of a-oriented crystals. A formation mechanism is discussed for the films and also in the context of general MFI nucleation and crystallization.

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