Journal
CRYSTENGCOMM
Volume 13, Issue 17, Pages 5285-5288Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ce05250k
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Funding
- NSFC [20871007, 20821091]
- National Basic Research Program of China [2006CB601102, 2009CB929403]
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The assembly of three simple achiral but acentric building blocks, protonated monoamine AH(+), formate HCOO- and Er3+, resulted in a series of chiral crystals of ammonium-templated erbium-formate frameworks with formula [AH+][Er(HCOO)(4)(-)], indicating that the increased opportunity to obtain chiral crystalline solids could be achieved by incorporating multiple acentric centers within the lattice.
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