4.7 Article

An unprecedented (5,12)-connected 3D self-penetrating metal-organic framework based on dinuclear barium clusters as building blocks

Journal

CRYSTENGCOMM
Volume 13, Issue 2, Pages 433-436

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00622j

Keywords

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Funding

  1. NSFC [20801044]
  2. China Postdoctoral Science Foundation [20080430205, 200902282]
  3. Science and Technology Foundation of Southwest University [SWUB2007035]
  4. Fundamental Research Funds for the Central Universities [XDJK2009B014]
  5. Program for Chongqing Excellent Talents in University

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An unprecedented binodal (5,12)-connected 3D self-penetrating metal-organic framework was first assembled from dinuclear barium clusters as 12-connected nodes and flexible ligands 4,4'-sulfonyldibenzoate as 5-connected nodes, and it represents the highest connected self-penetrating topology presently known for metal-organic frameworks.

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