Journal
CRYSTENGCOMM
Volume 12, Issue 12, Pages 4003-4006Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00199f
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Funding
- Babcock and Wilcox Company
- Department of Energy - Office of Fossil Energy
- U.S. Department of Energy [DE-AC05-76RL01830]
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Adsorption isotherms of pure gases present in flue and natural gas including CO2, N-2, CH4 and water were studied using Prussian blues of chemical formula M-3[Co(CN)(6)](2) (M = Cu, Ni, Mn). These materials adsorbed 8-12 wt% of CO2 at room temperature and 1 bar of pressure with heats of adsorption ranging from 6 to 16 kcal mol(-1).
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