Journal
CRYSTENGCOMM
Volume 12, Issue 11, Pages 3642-3650Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00176g
Keywords
-
Categories
Funding
- University of Garyounis in Libya
- EPSRC [EP/D062551/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/D062551/1] Funding Source: researchfish
Ask authors/readers for more resources
A series of six compartmental ligands, containing two or three bidentate chelating pyridyl-triazole or pyridyl-pyrazole units connected to a central aromatic spacer, has been used to prepare Pb(II) complexes which have been structurally characterised. Five of the complexes form infinite coordination networks including a one-dimensional chain and four two-dimensional sheets comprising three examples of (6,3) nets, and one example of a (4,4) net. One of the complexes is a discrete dinuclear dimeric complex in which two bridging ligands span two metal ions in a 'mesocate' box-like arrangement. The Pb(II) centres show a range of coordination numbers and geometries, from distorted six-coordinate with a stereochemically active lone pair of electrons, to fairly regular eight-coordinate with a square antiprismatic geometry.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available