Journal
CRYSTENGCOMM
Volume 12, Issue 12, Pages 4372-4377Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00135j
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Funding
- NSF of China [20803024, 20936001]
- SRF for ROCS (SEM)
- Ministry of Education of China [200805611045]
- Guangdong Natural Science Foundation [8151064101000094, 10351064101000000]
- Fundamental Research Funds for the Central Universities [2009ZZ0023]
- program for New Century Excellent Talents in Universities [NCET-08-0203]
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A new microporous europium-containing metal-organic framework [Eu-2(mu(2)-pzdc)(mu(4)-pzdc)(mu(2)-ox)(H2O)(4)]center dot 8H(2)O (1) (H(2)pzdc = 2,5-pyrazinedicarboxylic acid, H(2)ox oxalic acid) has been hydrothermally synthesized via an unprecedented in situ formation of 2,5-pyrazinedicarboxylate (pzdc) and oxalate (ox) ligands. Structure 1 was characterized by both single-crystal and powder X-ray diffraction analysis. It can be described as a 4-connected binodal Moganite network with the Schlafli symbol of (4.6(4).8)(2)(4(2).6(2).8(2)), which exhibits a reversible and highly selective sensing function with respect to acetone.
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