4.7 Article

Lone pair-pi vs pi-pi interactions in 5-fluoro-1-hexyluracil and 1-hexyluracil: a combined crystallographic and computational study

Journal

CRYSTENGCOMM
Volume 12, Issue 2, Pages 362-365

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b913111f

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Funding

  1. DGICYT of Spain [CTQ2009-12520-C03-03, CTQ2008-00841/BQU, CTQ2006-09339/BQU]
  2. Direccio General de Recerca, Desenvolupament Tecnologic i Innovacio del Govern Balear
  3. Conselleria d'Economia, Hisenda i Innovacio (Govern de les Illes Balears)

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The simple substitution of a hydrogen atom by a fluorine atom in 1-hexyluracil has an enormous consequence on the solid state structure due to the increment in the pi-acidity of the ring.

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