Journal
CRYSTENGCOMM
Volume 12, Issue 12, Pages 4124-4130Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00026d
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Funding
- NSFC [20673128, 20640430564, 20820102035]
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Cu1.94S-ZnS heterostructured nanorods are prepared by injecting Zn(acac)(2)-dodecanethiol solution into hot reaction systems containing Cu1.94S nanocrystals which catalyze the pyrolysis of Zn(acac)(2) and the following epitaxial growth of ZnS on Cu1.94S seeds. Crystallographic analysis suggests that the built-in p-n type heterostructures allow the dipole moment vectors of both the Cu1.94S head'' and ZnS tail'' to overlap, consequently giving rise to unexpected zipper-like self-assembled structures formed by the heterostructured Cu1.94S-ZnS nanorods.
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