Journal
CRYSTENGCOMM
Volume 12, Issue 11, Pages 3768-3772Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ce00122h
Keywords
-
Categories
Funding
- German Research Foundation [1362]
- Ruhr University Research School
Ask authors/readers for more resources
The deposition of five isostructural PCPs from the CPO-27-M (M = Ni, Co, Mg, Zn and Mn) family on top of amorphous Al2O3 was studied. The coatings were grown directly out of solvothermal mother solutions prepared following published procedures. Powder X-ray diffraction and scanning electron microscopy studies showed that when enough surface binding sites are available, continuous and uniform coatings of phase-pure CPO-27-Ni, Co and Mg are obtained. In the case of CPO-27-Zn and Mn, large crystals are spread onto the surface in a non-continuous fashion. The different morphologies suggest a strong effect of the cation nature on the growth mechanism and binding to the substrate. Activation and loading experiments were also performed in order to check the porosity of the films.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available